From Dusk Till Dawn
(1995)

Seth Gecko (George Clooney), and Kate Fuller (Juliette Lewis) are the only ones that survive the night.

Carlos comes and sees the vampires die and Seth yells at him for choosing that place to meet, then they do their trade.

Kate asks Seth to take her with him but he refuses.

The camera then zooms away showing catacombs under the Titty Twister.

Thanks Kyle!